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Download brick mansions full movie in hindi dubbed free download.New, simple and efficient methods to synthesize benzo[d]coumarins with excellent anti-inflammatory activity.
The 3-hydroxycoumarins are known to have anti-inflammatory activity. In this study, a new and simple method to prepare benzo[d]coumarins from commercially available 3-hydroxycoumarins was developed. Benzo[d]coumarins were synthesized from the novel 3-mono- and 3,4-di-O-benzoyloxycoumarins or from the novel 6-O-benzoyloxy-3-mono- and 3,4-di-O-benzoyloxycoumarins and 3-mono- and 3,4-di-O-benzoyloxycoumarins with a concomitant condensation-cyclization reaction. The anti-inflammatory activity of these new benzo[d]coumarins was tested by monitoring changes in the granulocyte elastase released from human polymorphonuclear leukocytes. Among them, the new benzo[d]coumarins derived from 6-O-benzoyloxy-3,4-di-O-benzoyloxycoumarin were the most potent inhibitors of human polymorphonuclear leukocyte elastase. The inhibitory potency of the compounds against human polymorphonuclear leukocyte elastase-activated by zymosan was 4-39 times stronger than that of diflunisal. In addition, the new benzo[d]coumarins did not inhibit cyclooxygenase. This simple synthesis protocol should be useful to prepare more derivatives with different structures.INTRODUCTION
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